Is this a proper usage of union - c++

Question

I want to have named fields rather than indexed fields, but for some usage I have to iterate on the fields. Dumb simplified example:
struct named_states {float speed; float position;};
#define NSTATES (sizeof(struct named_states)/sizeof(float))
union named_or_indexed_states {
struct named_states named;
float indexed[NSTATES];
}
...
union named_or_indexed_states states,derivatives;
states.named.speed = 0;
states.named.position = 0;
...
derivatives.named.speed = acceleration;
derivatives.named.position= states.named.speed;
...
/* This code is in a generic library (consider nstates=NSTATES) */
for(i=0;i<nstates;i++)
states.indexed[i] += time_step*derivatives.indexed[i];
This avoid a copy from named struct to indexed array and vice-versa, and replace it with a generic solution and is thus easier to maintain (I have very few places to change when I augment the state vector).It also work well with various compiler I tested (several versions of gcc/g++ and MSVC).
But theorically, as I understand it, it does not strictly adhere to proper union usage since I wrote named field then read indexed field, and I'm not sure at all we can say that they share same struct fields...
Can you confirm that's it's theorically bad (non portable)?
Should I better use a cast, a memcpy() or something else?
Apart theory, from pragmatic POV is there any REAL portability issue (some incompatible compiler, exotic struct alignment, planned evolutions...)?
EDIT: your answers deserve a bit more clarification about my intentions that were:
to let programmer focus on domain specific equations and release them from maintenance of conversion functions (I don't know how to write a generic one, apart cast or memcpy tricks which do not seem more robust)
to add a bit more coding security by using struct (fully controlled by compiler) vs arrays (decalaration and access subject to more programmer mistakes)
to avoid polluting namespace too much with enum or #define
I need to know
how portable/dangerous is my steering off the standard (maybe some compiler with aggressive inlining will use full register solution and avoid any memory exchange ruining the trick),
and if I missed a standard solution that address above concerns in part or whole.

Answer 1

There's no requirement that the two fields in named_states line up the same way as the array elements. There's a good chance that they do, but you've got a compiler dependency there.
Here's a simple implementation in C++ of what you're trying to do:
struct named_or_indexed_states {
named_or_indexed_states() : speed(indexed[0], position(indexed[1]) { }
float &speed;
float &position;
float indexed[2];
};
If the size increase because of the reference elements is too much, use accessors:
struct named_or_indexed_states {
float indexed[2];
float& speed() { return indexed[0]; }
float& position() { return indexed[1]; }
};
The compiler will have no problem inlining the accessors, so reading or writing speed() and position() will be just as fast as if they were member data. You still have to write those annoying parentheses, though.

Answer 2

Only accessing last written member of union is well-defined; the code you presented uses, as far as only standard C (or C++) is concerned, undefined behavior - it may work, but it's wrong way to do it. It doesn't really matter that struct uses the same type as the type of array - there may be padding involved, as well as other invisible tricks used by compiler.
Some compilers, like GCC, do define it as allowed way to achieve type-punning. Now the question arises - are we talking about standard C (or C++), or GNU or any other extensions?
As for what you should use - proper conversion operators and/or constructors.

Answer 3

This may be a little old-fashioned, but what I would do in this situation is:
enum
{
F_POSITION,
F_SPEED,
F_COUNT
};
float states[F_COUNT];
Then you can reference them as:
states[F_POSITION] and states[F_SPEED].
That's one way that I might write this. I'm sure that there are many other possibilities.